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The most difficult portion of the MCAT, as an aspiring doctor, is the tropylium ion m/z 91 benzyl cleavage mass fragmentation test (TC). The test focuses on distinguishing the positively charged ion from the negatively charged ion, and that’s a big difference! So, to pass the test, a doctor must understand how to break the benzyl cleavage bond. Here’s how: Tropylium ion is composed of a central positively charged ion surrounded by 4 electroneg
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In one of my early posts, I talked about the importance of being able to recognize benzyl cleavage and mass fragmentation in the titration of tropylium ions, specifically in the 91-benzyl moiety. To understand these two important techniques of titration, you need to know what they do. When you titrate a tropylium ions (the trophy in molecular science), you are looking for a clear peak in the titration curve. The trophy is formed by the benzyl mo
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