Why do 50 50 optical mixtures called racemic mixtures show zero optical rotation
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There are no real or stable optical isomers in chemistry, as is shown by optical rotations. The most common optical isomer is the molecule C-H-C where one hydrogen atom, or carbon atom, is missing (the carbocation), and there is no carrier electron. In a racemic mixture, each enantiomer (different stereoisomer, chiral center) has an isomeric form of a hydrocarbon group, and the sum of the hydrocarbon angles, in turn, gives a single rotation
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A racemic mixture of optically active species, such as alkanes, is a mixture in which two isomers or diastereomers exist in equal amounts, so their orientations in the molecule are equal and opposite, and all of the isomers appear in the same molecule or crystal. In many cases, a single racemic mixture may consist of isomers that differ only in their optical activity or physical properties, such as reactivity. The zero optical rotation refers to the fact that all of the isomers are
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Racemic mixtures consist of mixtures in which the same molecule is present in both the optical states. The optical rotation of any specific optical state (A, B or AB) of a molecule depends on the molecular structure and its intramolecular orientation. If a molecule is in one of the optical states (A, B or AB), it always shows zero optical rotation with any external field applied (with no applied field). For example, all the mixtures in Table 1 are Racemic
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Racemic mixtures have zero optical rotation because their optical dipole moment is 0. It does not have a net dipole moment due to the presence of identical molecules. Therefore the dipole moment of racemic mixtures is zero because the molecules are the same. The molecules in a racemic mixture cannot have different dipole moments, so there is no net dipole moment. If the molecules had different dipole moments then the dipole moments would cancel out, and the molecules would all be equal, giving zero optical rotation. visit
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